LOW-TEMPERATURE HEAT-CAPACITY AND MAGNETIC MEASUREMENTS OF URANIUM 3D-METAL HYDRIDES

Authors
Citation
M. Drulis, LOW-TEMPERATURE HEAT-CAPACITY AND MAGNETIC MEASUREMENTS OF URANIUM 3D-METAL HYDRIDES, Polish Journal of Chemistry, 71(12), 1997, pp. 1803-1808
Citations number
14
Categorie Soggetti
Chemistry
Journal title
ISSN journal
01375083
Volume
71
Issue
12
Year of publication
1997
Pages
1803 - 1808
Database
ISI
SICI code
0137-5083(1997)71:12<1803:LHAMMO>2.0.ZU;2-L
Abstract
Specific heats and magnetic properties as a function of temperature an d magnetic field for U6MH17 (M = Fe, Co, Mn and Ni) hydrides have been measured. These hydrides crystallize in the cubic Pm3n space group, l ike beta-UH3. The compounds are ferromagnets. The essential thermodyna mic functions of the entropy S and energy E for magnetic heat contribu tion were evaluated. It was established, that 3d-metals change the mag nitude of the magnetic anisotropy having, however a negligible influen ce on the magnetic transition temperature. The spin-reorientation tran sitions, suggested previously, were not confirmed.