ASYMMETRIC ACYLATION OF MESO-DIOLS WITH BENZOYL HALIDE IN THE PRESENCE OF A CHIRAL DIAMINE

Authors
ORIYAMA T IMAI K HOSOYA T SANO T
Citation
T. Oriyama et al., ASYMMETRIC ACYLATION OF MESO-DIOLS WITH BENZOYL HALIDE IN THE PRESENCE OF A CHIRAL DIAMINE, Tetrahedron letters, 39(5-6), 1998, pp. 397-400
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
5-6
Year of publication
1998
Pages
397 - 400
Database
ISI
SICI code
0040-4039(1998)39:5-6<397:AAOMWB>2.0.ZU;2-8
Abstract
Nonenzymatic desymmetrization of cis-1,2-cyclohexanediol by the asymme tric acylation with achiral benzoyl chloride in the presence of a chir al diamine derived from (S)-proline took place to give monobenzoate in high optical yield. (C) 1997 Elsevier Science Ltd. All rights reserve d.