METHYL 3,3-BIS(TRIALKYLSTANNYL)ACRYLATES - AN IMPROVED PREPARATIVE PROCEDURE

Authors
QUAYLE P WANG JY XU J URCH CJ
Citation
P. Quayle et al., METHYL 3,3-BIS(TRIALKYLSTANNYL)ACRYLATES - AN IMPROVED PREPARATIVE PROCEDURE, Tetrahedron letters, 39(5-6), 1998, pp. 479-480
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
5-6
Year of publication
1998
Pages
479 - 480
Database
ISI
SICI code
0040-4039(1998)39:5-6<479:M3-AIP>2.0.ZU;2-G
Abstract
Hydrostannylation of methyl (tri-n-butylstannyl)propiolate, 5, under f ree radical conditions provides ready access to the corresponding 3,3- bis(tri-alkylstannyl)acrylates. Hydrostannylation of 5 in the presence of Pd(O) affords the isomeric bis-stannane 7. (C) 1997 Published by E lsevier Science Ltd. All rights reserved.