NOVEL REACTION OF ALLYLIC ALCOHOLS WITH A HEXAFLUOROPROPENE-DIETHYLAMINE ADDUCT (PPDA) TO FORM RO-ALPHA-(TRIFLUOROMETHYL)-GAMMA,DELTA-UNSATURATED AMIDES

Authors
OGU K AKAZOME M OGURA K
Citation
K. Ogu et al., NOVEL REACTION OF ALLYLIC ALCOHOLS WITH A HEXAFLUOROPROPENE-DIETHYLAMINE ADDUCT (PPDA) TO FORM RO-ALPHA-(TRIFLUOROMETHYL)-GAMMA,DELTA-UNSATURATED AMIDES, Tetrahedron letters, 39(3-4), 1998, pp. 305-308
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
3-4
Year of publication
1998
Pages
305 - 308
Database
ISI
SICI code
0040-4039(1998)39:3-4<305:NROAAW>2.0.ZU;2-9
Abstract
Treatment of allylic alcohols (1) with a hexafluoropropene-diethylamin e adduct (PPDA) gave a-fluoro-(trifluoromethyl)-gamma,delta-unsaturate d amides (2), which were shown to be important precursors for synthesi zing a variety of fluoro(trifluoromethyl)methylene-containing compound s. (C) 1997 Elsevier Science Ltd. All rights reserved.