RADICAL CYCLIZATION OF BETA-ALKOXYACRYLATES - A FORMAL SYNTHESIS OF (-)-KUMAUSALLENE

Authors
LEE E YOO SK CHOO H SONG HY
Citation
E. Lee et al., RADICAL CYCLIZATION OF BETA-ALKOXYACRYLATES - A FORMAL SYNTHESIS OF (-)-KUMAUSALLENE, Tetrahedron letters, 39(3-4), 1998, pp. 317-318
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
3-4
Year of publication
1998
Pages
317 - 318
Database
ISI
SICI code
0040-4039(1998)39:3-4<317:RCOB-A>2.0.ZU;2-8
Abstract
Radical cyclization reaction of a bis(beta-alkoxyacrylate) intermediat e prepared from (-)-diethyl D-tartrate proceeded stereoselectively to give a 2,6-dioxabicyclo[3.3.0]octane product, which was converted into a known intermediate in the synthesis of kumausallene. (C) 1997 Elsev ier Science Ltd. All rights reserved.