A. Bennaim et R. Mazo, SIZE DEPENDENCE OF SOLVATION GIBBS ENERGIES - A CRITIQUE AND A REBUTTAL OF SOME RECENT PUBLICATIONS, JOURNAL OF PHYSICAL CHEMISTRY B, 101(51), 1997, pp. 11221-11225
The definition of the solvation Gibbs energy of a solute A in any solv
ent is repeated in exactly the same way as was done almost 20 years ag
o. Some recent publications that challenged this definition and sugges
tion ''correction'' terms; are critically examined. It is shown that t
hese newly suggested quantities are irrelevant to the solvation proces
s.