AMORPHOUS SN SI MIXED OXIDES, MILD SOLID LEWIS-ACID CATALYSTS FOR ESTERIFICATION AND ETHERIFICATION REACTIONS/

Citation
S. Storck et al., AMORPHOUS SN SI MIXED OXIDES, MILD SOLID LEWIS-ACID CATALYSTS FOR ESTERIFICATION AND ETHERIFICATION REACTIONS/, Journal of catalysis, 172(2), 1997, pp. 414-426
Citations number
44
Journal title
ISSN journal
00219517
Volume
172
Issue
2
Year of publication
1997
Pages
414 - 426
Database
ISI
SICI code
0021-9517(1997)172:2<414:ASSMOM>2.0.ZU;2-N
Abstract
Novel amorphous porous mixed oxides of Sn, Si, and Al were prepared by the sol-gel process for use as solid acid catalysts. The materials we re characterized by XRD, HRTEM, SEM, EDX, argon-physisorption, DRIFTS, and pyridine adsorption followed by FTIR. The catalysts show very few Bronsted sites and some Lewis acid sites. The pore architecture of th e materials was studied by the hydrocracking test of decane which indi cated weak activity but clear shape selectivity for most of the mixed oxides. Further catalytic testing included the direct esterification r eaction of pentaerythritol with stearic acid to pentaerythritoltetrast earate and the etherification of 1-hexanol and 1-naphthol with isobute ne. The esterification reaction was studied under reaction conditions close to industrial ones. The catalysts were found to be as active as commercial homogeneous and heterogeneous catalysts. While the activity found in the esterification reaction can be correlated with the incre ase in surface area and the decrease in Sn content, no correlation wit h microstructural parameters was found in the etherification reactions . (C) 1997 Academic Press.