C. Fuganti et al., ON THE MICROBIAL TRANSFORMATION OF ALPHA,BETA-UNSATURATED ARYL KETONES BY THE FUNGUS BEAUVERIA-BASSIANA, Journal of molecular catalysis. B, Enzymatic, 4(1-2), 1998, pp. 47-52
alpha,beta-unsaturated aryl ketones, 1a-12, have been submitted to the
action of the fungus Beauveria bassiana (ATCC 7159) in growing condit
ions. The saturation of the double bond strictly depends from the subs
tituent a to the carbonyl soup. The saturated ketone is then oxidised
in a Baeyer-Villiger type reaction. This new oxidative capacity of the
fungus has been studied and the adaptability of the micro organism to
wards structural modifications has been investigated. (C) 1998 Elsevie
r Science B.V.