Speciation of technogenic plutonium in various environmental objects i
s examined. The plutonium distribution throughout diverse forms of its
occurrence is controlled by its origin and the nature and physicochem
ical characteristics of the sample. The speciation of plutonium correl
ates with its distribution throughout the organic and mineral fraction
s of test samples. The mechanisms of Pu attachment to the mineral frac
tion and possible composition of compounds formed in it, and also the
contribution of separate groups of compounds of nonisotopic carriers i
n geochemical behavior of Pu in soils are discussed.