Cam. Deklein et al., SOIL ACIDIFICATION - A PROVISIONAL MODEL FOR NEW-ZEALAND PASTORAL SYSTEMS, New Zealand Journal of Agricultural Research, 40(4), 1997, pp. 541-557
Soil acidification is a major problem internationally and occurs in pa
storal systems as a result of nitrate leaching, nutrient transfer/remo
val, and soil organic matter (SOM) accumulation. Existing mechanistic
models on soil acidification calculate acidification rates retrospecti
vely, based on quantitative information on these acidifying processes.
This paper presents an outline of a predictive soil acidification mod
el that includes sub-models for estimating the extent of nitrate leach
ing, nutrient transfer/removal, and soil organic matter accumulation.
The model was used to predict acidification rates in a fertiliser tria
l on sheep-grazed pastures, receiving superphosphate fertiliser for 35
years. The predicted rates ranged from 1.46 to 3.83 kmol(c)/ha.year,
which was in moderate agreement with acid additions rates of 3.09 to 3
.43 kmol(c)/ha.year as calculated from measured changes in soil pH and
the pH buffer capacity (pHBC). Further development of the model is ne
eded to include a SOM accumulation sub-model and to refine the various
relationships within the existing sub-models. In addition, accurate i
nformation on the pHBC of soils is needed to convert soil pH change in
to acid addition rate, which will be crucial for validating the model.