METHANE CONVERSION IN THE FLOWING AFTERGLOW OF A DINITROGEN MICROWAVEPLASMA - INITIATION OF THE REACTION

The reaction of methane in the nitrogen afterglow is studied by combin ation of direct measurements and computer experiment. The experimental data were obtained by optical emission spectroscopy of the discharge, by gas chromatography of resulting stable products and by probe diagn ostics of charged species in afterglow plasma. The simulation was base d on a macroscopic kinetic approach covering 24 species and 61 reactio ns with input data given by the afterglow experiment. In the present s tage of the modelling the initiation of methane conversion was studied . It was found that, contrary to active discharge, in the afterglow pl asma the active neutral species (mainly excited dinitrogen molecules) are most important for the dissociation of methane into CHx and H radi cals.