The microstructural changes in worn surfaces of Mn6 and Mn13 steels be
fore and after wear were investigated by the use of SEM, TEM and a bac
k-scatter Mossbauer spectrometer. The results show that there exist tw
o kinds of austenite for austenitic manganese steels before wear, one
contains almost no carbon (C) and the other contains more C. The C ato
ms mainly exist in the octahedral interstitial sites of austenite. The
re is only one C atom as nearest neighbour around an iron atom. Corres
pondingly two kinds of friction-induced martensite are produced in the
worn surface of the Mn6 steel during wear. One is C-and metallic allo
ying element (Mn)-free martensite whose internal magnetic field value
equals 33.0 T and the other is C-and Mn-containing martensite whose in
ternal magnetic field value equals 30.7 T. The C-and Mn-free martensit
e is produced under low wear impact energy firstly and its fraction re
aches a saturated value rapidly. However, the C-and Mn-containing mart
ensite is produced under high wear impact energy and its fraction incr
eases with increasing impact energy of the wear test. No friction-indu
ced martensitic transformation in the Mn13 steel exists during wear. T
he friction-induced martensite mainly nucleates at the stress concentr
ation caused by plastic deformation such as the austenite grain bounda
ries and slip bands in the Mn6 steel. (C) 1997 Elsevier Science S.A.