Sa. Schofield et Re. Wyatt, COMPUTATIONAL STUDY OF MANY-DIMENSIONAL QUANTUM VIBRATIONAL-ENERGY REDISTRIBUTION .2. STATISTICS OF THE SPECTRUM WITH DYNAMICAL IMPLICATIONS, The Journal of chemical physics, 106(17), 1997, pp. 7047-7054
We continue a study in which we statistically analyze the dynamics of
vibrational energy flow in a model system of anharmonic oscillators wh
ich are nonlinearly coupled, with a local topology. Average spectra ar
e obtained from individual spectra of many basis states of similar ene
rgy, for different values of the magnitude of the coupling between sta
tes. The survival probabilities of the density are then determined fro
m the average spectra. When the average fluctuation in spectral intens
ities is small then the density survival probability closely follows t
he average survival probability presented in our earlier paper for sho
rt times. For longer times, when the average survival probability show
s a power law decay, this decay does not appear in the density surviva
l probability. In addition, when spectral fluctuations are large, the
two survival probabilities differ strongly. (C) 1997 American Institut
e of Physics.