Grapes of three white cultivars were treated with a commercial pectic
enzyme preparation on an industrial scale. The effect of enzyme treatm
ent on the following juice and wine volatiles was considered: fruity e
sters, terpenes, alcohols, volatile phenols (4-vinylphenol and 4-vinyl
guaiacol), hydroxycinnamate derivative esters (caftaric, coutaric, and
fertaric esters), and free hydroxy cinnamic acids (caffeic, coumaric
and ferulic acids), Pectic enzyme treatment increased the higher alcoh
ols, free hydroxycinnamic acids and volatile phenols, whereas amounts
of most esters, herbaceous alcohols and hydroxycinnamate derivative es
ters were reduced, Terpenes, 2-phenylethanol and benzyl alcohol levels
were not affected by pectic enzyme treatment. When tasted by an exper
t panel, differences were found in sensory characteristics, with wines
from untreated judged higher quality than those from treated grapes.