M. Masi et al., KINETICS OF INDIUM-PHOSPHIDE EPITAXIAL-GROWTH USING METAL-ORGANIC PRECURSORS, Crystal research and technology, 32(8), 1997, pp. 1125-1136
The deposition kinetics of InP using metal-organic precursors is prese
nted. The proposed chemical mechanism involves both gas phase and surf
ace reactions. The fundamental hypothesis adopted in deriving the mech
anism was a dual site dissociative adsorption of the precursors on the
growing surface. In any case, all the rate constants either were take
n from the literature or estimated through thermochemical methods. In
addition, the deposition reactor was simulated by means of a monodimen
sional model that accounts for the main reactor features through the b
oundary layer theory.