DISSOLUTION KINETICS OF GLASSY AND CRYSTALLINE AS2S3 IN AQUEOUS SODIUM SULFIDE AND HYDROXIDE

Authors
MAMEDOV SB MIKHAILOV MD
Citation
Sb. Mamedov et Md. Mikhailov, DISSOLUTION KINETICS OF GLASSY AND CRYSTALLINE AS2S3 IN AQUEOUS SODIUM SULFIDE AND HYDROXIDE, Journal of non-crystalline solids, 221(2-3), 1997, pp. 181-186
Citations number
13
Journal title
Journal of non-crystalline solids → ACNP
ISSN journal
00223093
Volume
221
Issue
2-3
Year of publication
1997
Pages
181 - 186
Database
ISI
SICI code
0022-3093(1997)221:2-3<181:DKOGAC>2.0.ZU;2-N
Abstract
Dissolution kinetics of glassy and crystalline As2S3 in aqueous sodium sulfide and hydroxide solutions was investigated. Glass, produced by rapid quenching contains frozen products of arsenic trisulfide dissoci ation - As4S4 and S. A strong change in the chemical behavior of g-and c-As2S3 has been found in its interaction with hydroxide ions. A mech anism of dissolving has been suggested. (C) 1997 Published by Elsevier Science B.V.