A comparative transport number study on a wide variety of lithium salt
s was performed, confirming the prevalence of an anionic transport in
most of the usual salts dissolved in a polyether network. A cationic t
ransport close to 0.5 was determined for several perfluorosulfonate ba
sed polymer electrolytes. The method used confirmed a transport number
close to unity for a perfluorosulfonate-based ionomer. (C) 1997 Elsev
ier Science S.A.