SUBMILLIMETER SPECTRUM AND STRUCTURE OF CHLORYL CHLORIDE, CLCLO2

Authors
MULLER HSP COHEN EA
Citation
Hsp. Muller et Ea. Cohen, SUBMILLIMETER SPECTRUM AND STRUCTURE OF CHLORYL CHLORIDE, CLCLO2, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(17), 1997, pp. 3049-3051
Citations number
17
Categorie Soggetti
Chemistry Physical
Journal title
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory → ACNP
ISSN journal
10895639
Volume
101
Issue
17
Year of publication
1997
Pages
3049 - 3051
Database
ISI
SICI code
1089-5639(1997)101:17<3049:SSASOC>2.0.ZU;2-H
Abstract
The submillimeter spectrum of ClClO2 has been observed between 365 and 398 GHz in a flowing system as a product of the FClO2 + HCl reaction. Absorptions of three isotopomers, (ClClO2)-Cl-35-Cl-35, (ClClO2)-Cl-3 7-Cl-35, and (ClClO2)-Cl-35-Cl-37, have been assigned. Rotational and centrifugal distortion constants have been determined and structural p arameters derived. The data are compared with those from a matrix-isol ation study, ab initio calculations, and related molecules.