To remove and retrieve Zn from galvanized scrap by electrolyzing with
caustic solution is experimentally confirmed to be a reasonable approa
ch and the galvanized scrap can be completely purified. The concentrat
ions of NaOH and ZnO, and the temperature of electrolyte are important
factors to influence the critical current density of passivation of Z
n layer. The electrolyzing parameters such as the applied current dens
ity, temperature of electrolyte, and the concentrations of NaOH and Zn
O are optimized by experiments.