RESONANT RAMAN-SCATTERING AND LUMINESCENCE IN CUINS2 CRYSTALS

Resonant Raman scattering and luminescence have been examined for CuIn S2 crystals grown by the traveling heater method (THM) and the iodine vapor transport method (IT). Resonant Raman spectra of CuInS2 have bee n observed, and the spectra show seven single-phonon peaks and one two -phonon peak. Among them, three single-phonon modes have been found in the low-Raman-shift region because of resonant enhancement of phonon modes. The enhancement of these phonon modes is caused by incoming res onance mediated by bound excitons on the THM crystal, while it is attr ibuted to outgoing resonance due to intermediate states of free excito ns on the IT crystal. (C) 1998 American Institute of Physics.