LITHIUM VANADIUM METASILICATE, LIVSI2O6

Citation
C. Satto et al., LITHIUM VANADIUM METASILICATE, LIVSI2O6, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1727-1728
Citations number
13
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
12
Pages
1727 - 1728
Database
ISI
SICI code
0108-2701(1997)53:<1727:LVML>2.0.ZU;2-K
Abstract
The title compound has been synthesized by solid-state reaction. Its s tructure is isomorphous with those of other lithium pyroxenes and is c omposed of infinite isolated chains of edge-sharing VO6 octahedra link ed together by corner-sharing SiO4 tetrahedra. These form. a three-dim ensional framework within which each Li+ ion occupies a highly distort ed octahedron.