KIS[(2,4,6-TRIISOPROPYLTHIO-PHENOLATO-S-S)GOLD(I)] DIETHYL-ETHER SOLVATE

Authors
LEBLANC DJ LOCK CJL
Citation
Dj. Leblanc et Cjl. Lock, KIS[(2,4,6-TRIISOPROPYLTHIO-PHENOLATO-S-S)GOLD(I)] DIETHYL-ETHER SOLVATE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1765-1768
Citations number
15
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
12
Pages
1765 - 1768
Database
ISI
SICI code
0108-2701(1997)53:<1765:KDS>2.0.ZU;2-R
Abstract
In the title compound, [Au6S6(C15H23)(6)](.)C4H10O, the gold-thiolate molecule, a centrosymmetric cyclic hexamer with a cyclohexane chair-li ke structure, lies about an inversion centre. The Au atoms are coordin ated in a near-linear fashion to bridging S atoms [Au-S 2.281 (2)-2.28 8 (3) Angstrom and S-Au-S 173.68 (9)-175.82 (9)degrees]. Bond lengths and angles are normal.