-MU-ACETATO-BIS[DICARBONYL(PYRAZOLE)-RUTHENIUM(I)] AND IS-[DICARBONYL(3,5-DIMETHYLPYRAZOLE)-RUTHENIUM(I)]

Citation
K. Panneerselvam et al., -MU-ACETATO-BIS[DICARBONYL(PYRAZOLE)-RUTHENIUM(I)] AND IS-[DICARBONYL(3,5-DIMETHYLPYRAZOLE)-RUTHENIUM(I)], Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1782-1784
Citations number
9
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
12
Pages
1782 - 1784
Database
ISI
SICI code
0108-2701(1997)53:<1782:-AI>2.0.ZU;2-J
Abstract
The crystal structures of the title compounds, [Ru-2-(C2H3O2)(2)(C3H4N 2)(2)(CO)(4)], (1), and [Ru-2(C2H3O2)(2)-(C5H8N2)(2)(CO)(4)], (2), hav e been determined, The octahedral coordination about the Ru-1 ion is s lightly distorted in (1) and more distorted in (2), with the two O ato ms and two C atoms in the equatorial positions, and one N atom and ano ther Ru ion in the axial positions. Compound (2) has mirror symmetry.