THE 1 1-ANTIMONY-TRICHLORIDE ADDUCT OF CHLOROBIS(2,6-DIMETHYLPIPERIDIN-1-YL)PHOSPHINE OXIDE/

Authors
VIJJULATHA M SWAMY KCK HUCH V VEITH M
Citation
M. Vijjulatha et al., THE 1 1-ANTIMONY-TRICHLORIDE ADDUCT OF CHLOROBIS(2,6-DIMETHYLPIPERIDIN-1-YL)PHOSPHINE OXIDE/, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1789-1791
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
12
Pages
1789 - 1791
Database
ISI
SICI code
0108-2701(1997)53:<1789:T11AOC>2.0.ZU;2-2
Abstract
In the structure of the title complex, [(C7H14N)(2)ClP(O)].SbCl3, the Sb atom shows a distorted trigonal bipyramidal geometry (including the lone pair). The O-Sb interaction of antimony with the phosphoryl O at om is only moderate and is weaker than that observed in the known comp ound Cl3PO-->SbCl5.