TRIS(1-PHENACYL-2-PYRIDONE) HYDROXONIUM TETRAFLUOROBORATE, A HYDROGEN-BONDED COMPLEX

Authors
ZHUKOV SG RYBAKOV VB BABAEV EV PASESHNICHENKO KA SCHENK H
Citation
Sg. Zhukov et al., TRIS(1-PHENACYL-2-PYRIDONE) HYDROXONIUM TETRAFLUOROBORATE, A HYDROGEN-BONDED COMPLEX, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1909-1911
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
12
Pages
1909 - 1911
Database
ISI
SICI code
0108-2701(1997)53:<1909:THTAH>2.0.ZU;2-V
Abstract
The hydrolytic cleavage of 2-phenyloxazolo[3,2-a]-pyridinium tetrafluo roborate results in the formation of the title tris(1-phenacyl-2-pyrid one) hydroxonium tetrafluoroborate complex, 3C(13)H(11)NO(2) . H3O+BF4 -. The structure is built up from hydrogen-bonded cations and disorder ed BF4- anions. The strong hydrogen bonding causes considerable redist ribution of electron density in the pyridone moiety.