2-HYDROXY-5,5-DIMETHYLCYCLOHEX-2-EN-1-ONE

Citation
D. Ulku et al., 2-HYDROXY-5,5-DIMETHYLCYCLOHEX-2-EN-1-ONE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1998-1999
Citations number
14
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
12
Pages
1998 - 1999
Database
ISI
SICI code
0108-2701(1997)53:<1998:2>2.0.ZU;2-C
Abstract
The structure of the title compound, C8H12O2, which is a rearrangement product of the reaction of 6-hydroxy-4,4-dimethylcyclohex-2-en-1-one and 4-dimethylaminopyridine has been identified as 2-hydroxy-5,5-dimet hylcyclohex-2-en-1-one, The C atom of the six-membered ring connected to the two methyl groups is 0.617(2)Angstrom out of the least-squares plane defined by the other C atoms of the rin. The unit cell consists of discrete molecules with intra-and intermolecular hydrogen bonds.