C. Lacroix et al., RELATIONSHIPS BETWEEN RHEOLOGY AND MORPHOLOGY FOR IMMISCIBLE MOLTEN BLENDS OF POLYPROPYLENE AND ETHYLENE COPOLYMERS UNDER SHEAR-FLOW, Journal of rheology, 42(1), 1998, pp. 41-62
The linear and nonlinear viscoelastic properties of immiscible polymer
blends propylene/ethylenevinylacetate-ethylenemethylacryl [PP/(EVA-EM
A)] have been investigated. The transient shear flow experiments refle
ct the structural changes of the blends during the flow. Overshoots in
stress growth experiments are observed when the dispersed phase is de
formable. In this case, a good description of these transient rheologi
cal data is obtained using modified versions of the Lee and Park [J. R
heol. 38, 1405 (1994)] and the Grmela and Ait-Kadi [J. Non-Newtonian F
luid Mech. 55, 191 (1994)] models. Predictions of the morphological ev
olution of the blend under transient shear flows were calculated from
the modified models which are shown to describe the breakup and coales
cence phenomena under moderately large deformation shear flow. When th
e dispersed phase is undeformable, these models, which are either base
d on the original Doi and Ohta [J. Chem. Phys. 95, 1242 (1991)] theory
or derived to retrieve an extension of the Doi-Ohta theory [Lee and P
ark, J. Rheol. 38, 1405 (1994)], predict phase separation in contrast
to the experimental evidence of stable emulsion. The Palierne emulsion
model [Rheol. Acta 29, 201 (1990)] is used to characterize the linear
viscoelastic properties of the blend before and after the transient s
hear experiments. (C) 1998 The Society of Rheology.