THE STRUCTURE OF [C12H14N2](3)[BICL6](2)CENTER-DOT-2H(2)O AT ROOM-TEMPERATURE

Authors
BLACHNIK R JASCHINSKI B REUTER H KASTNER G
Citation
R. Blachnik et al., THE STRUCTURE OF [C12H14N2](3)[BICL6](2)CENTER-DOT-2H(2)O AT ROOM-TEMPERATURE, Zeitschrift fur Kristallographie, 212(12), 1997, pp. 874-877
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Zeitschrift fur Kristallographie → ACNP
ISSN journal
00442968
Volume
212
Issue
12
Year of publication
1997
Pages
874 - 877
Database
ISI
SICI code
0044-2968(1997)212:12<874:TSO[AR>2.0.ZU;2-2
Abstract
At room temperature, tris(1,1'-dimethyl-4-4'-bipyridinium) bishexachlo robismuthat(3-) dihydrate, [C12H14N2](3)[BiCl6](2) . 2 H2O crystallize s in the triclinic space group C-i(1); P (1) over bar; (No. 2) with a = 797.0(2) pm, b = 1215.8(2) pm, c = 1303.9(3) pm, alpha = 88.76(1)deg rees, beta = 83.01(1)degrees, gamma = 73.86(1)degrees, Z = 1, D-x = 1. 977 g/cm(3). The cell contains three [C12H14N2](2+) cations (methyl vi ologen), two slightly distorted BiCl6 octahedra ((d) over bar(Bi-Cl) = 269.4(2) pm) and two water molecules.