ANALYSIS OF THE ELECTROCAPILLARY CURVES AND ADSORPTION PROCESS MODELSIN COPPER-PARALLEL-TO-BORON+ALUMINIUM OXIDE MELT

Authors
KOBELEV OA SOTNIKOV AI KOBELEV AV
Citation
Oa. Kobelev et al., ANALYSIS OF THE ELECTROCAPILLARY CURVES AND ADSORPTION PROCESS MODELSIN COPPER-PARALLEL-TO-BORON+ALUMINIUM OXIDE MELT, Zeitschrift für physikalische Chemie, 203, 1998, pp. 143-158
Citations number
46
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Zeitschrift für physikalische Chemie → ACNP
ISSN journal
09429352
Volume
203
Year of publication
1998
Part
1-2
Pages
143 - 158
Database
ISI
SICI code
0942-9352(1998)203:<143:AOTECA>2.0.ZU;2-P
Abstract
We analyzed the electrocapillary curves (ecc) sigma(phi) of pure coppe r and copper doped with 0.05 mass % of sulfur at 1200 degrees C in con tact with boron + aluminium oxide electrolyte. The influence of interf ace-active particles on electrocapillary features was analyzed using t he Langmuir isotherm approximation taking into account competitive ads orption and the shift in the potential of zero charge (pzc).