The authentication and quality assessment of virgin olive oil were per
formed using high-resolution H-1 and C-13 NMR spectroscopy. An overvie
w of the various determinations currently assessed is presented with e
mphasis on the detection of adulteration with foreign (seed) oils and
esterified or refined olive and olive-pomace oils, Recent results on t
he NMR analysis of natural compounds (diacylglycerols, free fatty acid
s, aldehydes, polyphenols, etc.) related to the quality-freshness of v
irgin olive oil are also reported. The possible contribution of high-r
esolution NMR to the authentication of geographical origin of virgin o
live oil is discussed. (C) 1997 John Wiley & Sons, Ltd.