The biexciton formation in (Cd, Zn)Se/ZnSe quantum dots (QDs) is studi
ed by using time-resolved photoluminescence (PL) spectroscopy. Analyzi
ng the spectral lineshape of the biexciton signal, an increase of the
biexciton binding energy is observed with decreasing dot size due to t
he influence of the carrier and the dielectric confinement in QDs. In
addition. a faster rise time of the biexciton luminescence signal indi
cates an enhanced biexciton formation coefficient in totally confined
systems as compared to a quasi-two dimensional reference.