STEREOSELECTIVE ALKENYLATION OF ACTIVATED OLEFINS VIA NICKEL-CATALYZED ELECTROREDUCTIVE COUPLING

Authors
CONDONGUEUGNOT S DUPRE D NEDELEC JY PERICHON J
Citation
S. Condongueugnot et al., STEREOSELECTIVE ALKENYLATION OF ACTIVATED OLEFINS VIA NICKEL-CATALYZED ELECTROREDUCTIVE COUPLING, Synthesis, (12), 1997, pp. 1457-1460
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
12
Year of publication
1997
Pages
1457 - 1460
Database
ISI
SICI code
0039-7881(1997):12<1457:SAOAOV>2.0.ZU;2-Q
Abstract
The nickel-catalyzed electroreductive conjugate addition of (Z)- or (E )-alkenyl halides to electron-deficient olefins in the presence of a s acrificial iron rod as the anode proceeds with complete retention of t he stereochemistry of the alkenyl part and affords functionalized isom erically pure (Z)- or (E)-olefins in high yield.