DETERMINATION OF THE CHARGE-TRANSFER PARAMETERS OF 4,4'-(FERROCENE-1,1'-DIYLDIVINYLENE) BIS(BENZO-15-CROWN-5) AT GLASSY-CARBON ELECTRODE

Electrochemical parameters of errocene-1,1'-diyldivinylene)bis(benzo-1 5-crown-5) were collected using cyclic voltammetry, chronoamperometry and chronopotentiometry at a glassy carbon electrode. One-electron qua si-reversible oxidation wave was obtained at E-pn of 0.532 V and E-pc of 0.387 V. The peak separation, Delta E-p, standard heterogeneous rat e constant, k(0), and diffusion coefficient, D, of the electrochemical species have been processed by convolution and deconvolution transfor mations. Digital simulations using the kinetic parameters were also pe rformed.