Three-dimensional solid superstructures built with submicrometric SiO2
spheres ordered in a close packed arrangement are shown to behave as
photonic crystals. Spheres are synthesised following the Stober-Fink-B
ohn method. A close packed structure with a perfect short-range order
(tens of microns) is then obtained by sedimentation, on suitable subst
rates. Specular reflectance of visible light is found to follow Bragg'
s law which indicates that these structures behave as photonic crystal
s. This work shows that the ordering of microparticles can be a method
to build photonic bandgap materials. (C) 1997 Academic Press Limited.