UNCATALYZED OXIDATION OF CYCLOHEXANE IN A CONTINUOUS REACTOR

Citation
Y. Wen et al., UNCATALYZED OXIDATION OF CYCLOHEXANE IN A CONTINUOUS REACTOR, Chemical Engineering Science, 52(24), 1997, pp. 4593-4605
Citations number
26
Categorie Soggetti
Engineering, Chemical
ISSN journal
00092509
Volume
52
Issue
24
Year of publication
1997
Pages
4593 - 4605
Database
ISI
SICI code
0009-2509(1997)52:24<4593:UOOCIA>2.0.ZU;2-3
Abstract
This paper examines the kinetics of the oxidation of cyclohexane. Reco gnising that catalytic effects of the reactor wall may impact on the k inetics of organic oxidations, especially in laboratory scale reactors , these experiments are conducted in an aluminium reactor. In addition , a novel technique is introduced which permits these oxidation reacti ons to be studied without the intervention of gas-liquid mass transfer and thus yields homogeneous kinetics data. A kinetic model for the re action is proposed. (C) 1997 Elsevier Science Ltd.