This paper examines the kinetics of the oxidation of cyclohexane. Reco
gnising that catalytic effects of the reactor wall may impact on the k
inetics of organic oxidations, especially in laboratory scale reactors
, these experiments are conducted in an aluminium reactor. In addition
, a novel technique is introduced which permits these oxidation reacti
ons to be studied without the intervention of gas-liquid mass transfer
and thus yields homogeneous kinetics data. A kinetic model for the re
action is proposed. (C) 1997 Elsevier Science Ltd.