Optical characterization of the oxygen dimer in silicon has been perfo
rmed for the first time. The vibrational IR absorption bands at 1012,
1060, and 1105 cm(-1) are shown to arise from this complex. Using heat
-treatment studies, the dimer binding energy is determined to be about
0.3 eV. Indications of the high migration ability of the dimer predic
ted earlier are found as well.