Lateral force microscopy (LFM) images on polymeric and inorganic subst
rates demonstrate how water is transported to and from a substrate by
the capillary formed by the LFM tip and sample. Although it is known t
hat water qualitatively affects the atomic force microscopy and LFM me
asurements, herein we report the condition dependent range of sizes of
the water menisci formed in the capillary during such measurements. T
he effect of water in air can change the force of friction by a factor
greater than or equal to 2, with the magnitude of this effect depende
nt on the chemical nature of the sample and tip dynamics. These result
s have important implications for any analytical measurement-of fricti
on by LFM in air.