WATER-IN-OIL EMULSIONS - ROLE OF THE SOLVENT MOLECULAR-SIZE ON DROPLET INTERACTIONS

We prepare monodisperse inverted (water-in-oil) emulsion droplets and observe their phase behavior in various types of nonaqueous continuous phases. By using linear polydimethylsiloxanes or linear alkanes of le ngth n (monomer units), mixed at volume fraction phi with dodecane, we determine the boundary within the phi/n plane which describes the col loidal aggregation. In the limit of large n, the boundary is well pred icted by a hard core depletion model of polymer chains. Deviations to this prediction become increasingly pronounced as n is reduced.