SYNTHESIS OF NEW ADSORBENT COPPER(II) TEREPHTHALATE

Copper(II) terephthalate absorbs a large amount of gases such as N-2, Ar, O-2, and Xe. The maximum amounts of absorption of gases were 1.8, 1.9, 2.2, and 0.9 mole per one mole of the copper(II) salt for N-2, Ar , O-2, and Xe, respectively, indicating that the gases were not adsorb ed on the surface but occluded within the solid. The porous structure of copper(II) terephthalate, in which the gas is occluded, is deduced from the temperature dependence of magnetic susceptibilities and the l inear structure of terephthalate.