CONVERSION OF THE VALENCE STATES OF FE-57 ATOMS PRODUCED IN CO-57-LABELED [CO(PYRIDINE)(2)NI(CN)(4)]

Authors
SATO T AMBE F KITAZAWA T SANO H TAKEDA M
Citation
T. Sato et al., CONVERSION OF THE VALENCE STATES OF FE-57 ATOMS PRODUCED IN CO-57-LABELED [CO(PYRIDINE)(2)NI(CN)(4)], Chemistry Letters, (12), 1997, pp. 1287-1288
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
12
Year of publication
1997
Pages
1287 - 1288
Database
ISI
SICI code
0366-7022(1997):12<1287:COTVSO>2.0.ZU;2-1
Abstract
Emission Mossbauer spectra of the title compound measured below 80K co nsist of three components ascribed to two Fe(II) high-spin states and one Fe(III) low-spin state. It was concluded that a part of the Fe(II) high-spin species converts to an Fe(III) high-spin species above 210 K, based on the comparison of the results with temperature-depending s pin-crossover transition of the isomorphous compound, [Fe(py)(2)Ni(CN) (4)].