WEAKLY-BOUND OXYGEN IN THE CATALYTIC CO OXIDATION AND EXOEMISSION FROM COMPLEX OXIDES HAVING A SPINEL STRUCTURE

Authors
KRYLOVA IV PIROGOVA GN PANICH NM
Citation
Iv. Krylova et al., WEAKLY-BOUND OXYGEN IN THE CATALYTIC CO OXIDATION AND EXOEMISSION FROM COMPLEX OXIDES HAVING A SPINEL STRUCTURE, Russian chemical bulletin, 46(9), 1997, pp. 1543-1545
Citations number
17
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
9
Year of publication
1997
Pages
1543 - 1545
Database
ISI
SICI code
1066-5285(1997)46:9<1543:WOITCC>2.0.ZU;2-Y
Abstract
The catalytic activity of complex oxides (MM2O4)-M-I-O-II (M-I = Cu, N i, Co, Zn, or Mg; M-II Mn or Cr) with a spinel structure in the oxidat ion of CO and the low-temperature (20-400 degrees C) exoemission of ne gative charges from their surface were investigated. A relationship be tween the catalytic activity and the emissivity of the systems under s tudy was found. The role of the charged species of weakly bound oxygen in exoemission and oxidative catalysis by the complex oxides is discu ssed.