CRYSTAL AND MOLECULAR-STRUCTURE OF THE COMPLEX-RADICAL IONIC SALT, N-(BETA-IODOETHYL)PYRIDINIUM BIS(7,7',8,8'-TETRACYANOQUINODIMETHANIDE), )(-DOT(TCNQ)(CENTER-DOT-)CENTER-DOT(TCNQ)()CENTER)

Authors
DYACHENKO OA GRITSENKO VV ABASHEV GG SHKLYAEVA EV RUSSKIKH VS
Citation
Oa. Dyachenko et al., CRYSTAL AND MOLECULAR-STRUCTURE OF THE COMPLEX-RADICAL IONIC SALT, N-(BETA-IODOETHYL)PYRIDINIUM BIS(7,7',8,8'-TETRACYANOQUINODIMETHANIDE), )(-DOT(TCNQ)(CENTER-DOT-)CENTER-DOT(TCNQ)()CENTER), Russian chemical bulletin, 46(9), 1997, pp. 1555-1559
Citations number
11
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
9
Year of publication
1997
Pages
1555 - 1559
Database
ISI
SICI code
1066-5285(1997)46:9<1555:CAMOTC>2.0.ZU;2-B
Abstract
A complex radical ionic salt, N-(beta-iodoethyl)pyridinium bis(7,7',8, 8'-tetracyanoquinodimethanide), (C7H9IN)(+).(TCNQ)(.-).(TCNQ), where T CNQ is 7,7',8,8'-tetracyanoquinodimethane, was synthesized and studied by X-ray structural analysis. The crystal structure of the complex co nsists of layers. Layers of (C7H9IN)(+) cations alternate with layers of TCNQ molecules packed in stacks. Shortened intermolecular contacts occur in stacks of TCNQ and between cationic and anionic layers.