REACTION OF CYCLOPENTADIENYLLUTETIUM ANTHRACENIDE WITH AZOBENZENE - SYNTHESIS AND MOLECULAR AND CRYSTAL-STRUCTURE OF THE BINUCLEAR COMPLEX [C5H5(THF)LU(MU-ETA(2)ETA(2)-PHN-NPH)](2)(THF)(2) AND ITS DYNAMIC BEHAVIOR IN SOLUTION

Authors
ROITERSHTEIN DM LYSSENKO KA BELYAKOV PA ANTIPIN MY PETROV ES
Citation
Dm. Roitershtein et al., REACTION OF CYCLOPENTADIENYLLUTETIUM ANTHRACENIDE WITH AZOBENZENE - SYNTHESIS AND MOLECULAR AND CRYSTAL-STRUCTURE OF THE BINUCLEAR COMPLEX [C5H5(THF)LU(MU-ETA(2)ETA(2)-PHN-NPH)](2)(THF)(2) AND ITS DYNAMIC BEHAVIOR IN SOLUTION, Russian chemical bulletin, 46(9), 1997, pp. 1590-1594
Citations number
10
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
9
Year of publication
1997
Pages
1590 - 1594
Database
ISI
SICI code
1066-5285(1997)46:9<1590:ROCAWA>2.0.ZU;2-2
Abstract
The reaction of the cyclopentadienyllutetium anthracenide, C5H5Lu(C14H 10)(2-)(THF)(2) (1), with azobenzene yielded the [C5H5(THF)Lu(mu-eta(2 ):eta(2)-PhN-NPh)](2)(THF)(2) (2) binuclear complex. The structure of the reaction product was established by X-ray structural analysis. The dynamic behavior of complex 2 in a THF-d(g) solution was studied by H -1 NMR spectroscopy in the temperature range of 265-330 K.