STEREOCONTROLLED SYNTHESIS OF (-IRIDOMYRMECIN AND (-)-IRIDOMYRMECIN FROM CITRONELLENE ENANTIOMERS())

Authors
STEPANOV AV VESELOVSKY VV
Citation
Av. Stepanov et Vv. Veselovsky, STEREOCONTROLLED SYNTHESIS OF (-IRIDOMYRMECIN AND (-)-IRIDOMYRMECIN FROM CITRONELLENE ENANTIOMERS()), Russian chemical bulletin, 46(9), 1997, pp. 1606-1610
Citations number
10
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
9
Year of publication
1997
Pages
1606 - 1610
Database
ISI
SICI code
1066-5285(1997)46:9<1606:SSO(A(>2.0.ZU;2-B
Abstract
Natural (+)-iridomyrmecin and its unnatural enantiomer (-)-iridomyrmec in were synthesized by intramolecular [3+2] dipolar cycloaddition of s ilyl nitronates that had been generated from the nitro derivatives of (+)- and (-)-citronellenes, respectively.