PREPARATION OF TRIBROMOGERMYLCYCLOPROPANES BY INSERTION OF DIBROMOGERMYLENE INTO THE C-BR BONDS OF 1,1-DIBROMO-2-TRIMETHYLSILYLCYCLOPROPANE

Authors
SHCHERBININ VV PAVLOV KV SHVEDOV IP KORNEVA OS MENCHIKOV LG NEFEDOV OM
Citation
Vv. Shcherbinin et al., PREPARATION OF TRIBROMOGERMYLCYCLOPROPANES BY INSERTION OF DIBROMOGERMYLENE INTO THE C-BR BONDS OF 1,1-DIBROMO-2-TRIMETHYLSILYLCYCLOPROPANE, Russian chemical bulletin, 46(9), 1997, pp. 1628-1629
Citations number
7
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
9
Year of publication
1997
Pages
1628 - 1629
Database
ISI
SICI code
1066-5285(1997)46:9<1628:POTBIO>2.0.ZU;2-5
Abstract
The reaction of 1,1-dibromo-2-trimethylsilylcyclopropane with dibromog ermylene generated from its dioxane complex made it possible to obtain for the first time the products of insertion of dibromogermylene into one or both C-Br bonds of the dibromocyclopropane. Under similar cond itions, alkyl-substituted gem-dibromocyclopropanes give only alkenyl-g ermanes resulting from isomerization of the corresponding cyclopropyl- substituted tribromogermanes.