E. Juzeliunas et K. Juttner, ELECTROCHEMICAL STUDY OF NO CONVERSION FROM FE(II)-EDTA-NO COMPLEX ONPT ELECTRODES, Journal of the Electrochemical Society, 145(1), 1998, pp. 53-58
Citations number
28
Categorie Soggetti
Electrochemistry,"Materials Science, Coatings & Films
The Fe(LI)-ethylenediaminetetraacetic acid (EDTA)-NO complex formed by
interaction of gaseous nitrous oxide (ca. 200 ppm) and Fe(II)-EDTA in
aqueous solution was found to be converted electrochemically on plati
num electrodes at potentials below ca. -0.6 V-SCE indicating the catho
dic reduction of NO. In addition to our previous studies by which the
indirect conversion of NO with dithionite as a redox mediator was conf
irmed, the present results should elucidate the possibility of the dir
ect electrochemical conversion of NO in mediator-free solutions. To cl
early separate this process from other reactions in the system, the el
ectrochemical behavior of Fe(II)-EDTA and Fe(III)-EDTA was studied ove
r a wide potential range at different pH values. Five electrode reacti
ons could be identified, which include the oxidation/reduction of Fe2/Fe3+ in the EDTA complex, the reduction of EDTA, the-reduction of pro
tons, the cathodic deposition of iron, and the anodic decomposition of
EDTA. The electrochemical deposition of iron from Fe(II)-EDTA at pote
ntials E < -1.0 V-SCE was confirmed by electrochemical quartz crystal
microbalance measurements and energy-dispersive x-ray analysis.