The Tunguska basin, eastern Siberia, contains 3.5-8 km of Late Precamb
rian to Triassic sedimentary and igneous rocks. Source-reservoir-seal
systems are present throughout the Upper Precambrian to Permo-Carbonif
erous interval. Hydrocarbon generation and accumulation largely preced
ed the formation of the Siberian traps, a Late Permian to Middle Trias
sic association of effusive and explosive extrusives and intrusive dol
erites. The intrusives occur mainly in Palaeozoic strata and have prof
oundly affected hydrocarbon accumulation. The major process is of dest
ruction of hydrocarbon accumulations, owing to the fact that substanti
al volumes of the Palaeozoic basin fill has been heated to 150 degrees
C plus. At lower temperatures experienced further from the contacts b
etween the intrusions and the country rocks, organic matter thermal ma
turation levels may significantly exceed those related to burial alone
. Water-mineral-hydrocarbon interactions in association with magmatic
heating have produced a range of effects, including the generation of
hydrocarbons rich in sulphur compounds such as mercaptans.