The most general S-paired systems of fermions for which a gap equation
can be separated according to the specific redefined variables, are c
onsidered. Moreover, a solution of this gap equation (gap energy) is o
btained in a parametric form. It allows us to investigate thermodynami
c properties of such systems i.e. the thermodynamic potential, entropy
, heat capacity and critical magnetic induction. We show also that the
heat capacity difference between the superconducting and the normal p
hase is entirely determined by the order parameter. The obtained resul
ts reveal possibilities of discontinuous phase transition to the norma
l state and moreover, the theorem on existence of such transitions is
formulated and proved. The condition for the BCS-type energy gap is gi
ven, which additionally classifies properties of the heat capacity of
S-paired phase by virtue of the shape of the energy gap. In order to i
llustrate the developed formalism, the numerical results for the so-ca
lled statistical spin liquids and application of the established metho
ds to the experimental data conversion, are presented and discussed.