[RU(ETA(5)-C5ME5)(ME2NCH2CH2NME2)](-ELECTRON COMPLEX - REACTION WITH DIOXYGEN AND FORMATION OF A MONOMERIC HYDROXORUTHENIUM TETRAMETHYLFULVENE COMPLEX(), A STABLE 16)

Authors
GEMEL C MEREITER K SCHMID R KIRCHNER K
Citation
C. Gemel et al., [RU(ETA(5)-C5ME5)(ME2NCH2CH2NME2)](-ELECTRON COMPLEX - REACTION WITH DIOXYGEN AND FORMATION OF A MONOMERIC HYDROXORUTHENIUM TETRAMETHYLFULVENE COMPLEX(), A STABLE 16), Organometallics, 16(26), 1997, pp. 5601-5603
Citations number
24
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
26
Year of publication
1997
Pages
5601 - 5603
Database
ISI
SICI code
0276-7333(1997)16:26<5601:[C-RWD>2.0.ZU;2-X
Abstract
NaBAr4' (Ar' = 3,5-C6H3(CF3)(2)) abstracts chloride from Ru(eta(5)-C5M e5)(Me2NCH2CH2NMe2)Cl (1) in Et2O to give the stable cationic 16e comp lex [Ru(eta(5)-C5Me5)(Me2NCH2CH2NMe2)]BAr4' (2). Exposure of a Et2O so lution of 2 to air at room temperature yields the novel monomeric hydr oxotetramethylfulvene complex [Ru(eta(6)-C5Me4CH2)(Me2NCH2CH2NMe2)(OH) ]BAr4' (4).