A NOVEL ORGANOLEAD(II) SPECIES, THE PLUMBACYCLOALKANE DERIVATIVE [CH2SIME2C(SIME3)(2)PBC(SIME3)(2)SIME2CH2]

Authors
EABORN C GANICZ T HITCHCOCK PB SMITH JD SOZERLI SE
Citation
C. Eaborn et al., A NOVEL ORGANOLEAD(II) SPECIES, THE PLUMBACYCLOALKANE DERIVATIVE [CH2SIME2C(SIME3)(2)PBC(SIME3)(2)SIME2CH2], Organometallics, 16(26), 1997, pp. 5621-5622
Citations number
11
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
26
Year of publication
1997
Pages
5621 - 5622
Database
ISI
SICI code
0276-7333(1997)16:26<5621:ANOSTP>2.0.ZU;2-Y
Abstract
The title lead(II) derivative was obtained as dark blue crystals by tr eatment of PbCl2 with EDA)(2)][CH2SiMe2C(SiMe3)(2)LiC(SiMe3)(2)SiMe2CH 2] (TMEDA = N,N,N',N'-tetramethylethylenediamine) in tetrahydrofuran a nd its structure determined by X-ray diffraction. The compound is in. effect the first dialkylead(II) species to be structurally characteriz ed. The C-Pb-C angle is 117.1(2)degrees. Analogous treatment of SnCl2 yielded a yellow solid, which was judged from spectroscopic data to be the TMEDA complex of the analogous stannacycloalkane.